Abstract:While promoting technological innovation,the rational market structure is often subjected to the impact of non market factors. The precise depiction of the mechanism of market and administrative factors on innovation will seriously affect the power and ability of technological innovation in the new era. This paper, based on the concrete practice of China''s high-tech industry, uses the panel fixed effect model and the panel random frontier production model to study the impact of market structure and administrative barriers on enterprise technology. The results are as follows: the first, innovation is a normal behavior of the enterprise under the frontier production line of technological innovation ability in the aspect of innovation efficiency; the second, in terms of innovation power, the market structure has different nonlinear effects on enterprise innovation under different administrative barriers, and the market structure can also act independently on the innovation power of the enterprise by itself; the third, in the aspect of innovation ability, when the market structure is combined with administrative barriers only, the market structure can play an important role in enterprise''s innovation ability. Therefore, in the process of enterprise technological innovation, we should pay more attention to the linkage mechanism of administrative policy and market policy while optimizing and adjusting the market structure.