Abstract:The eco industrial park is a complex system. It is composed of many enterprises and embedded relations. The ecological enterprises in the garden constitute the "industrial ecological chain network". The enterprises in the chain network promote and mutually benefit each other, and constitute the industrial coupling symbiotic network system. In order to analyze the development level of the industrial coupling symbiotic network in the eco industrial park, the grey relational model is used to evaluate the ecological efficiency of the industrial coupling symbiotic network of the oil and gas resource-based urban eco industrial park. The results show that the industry coupling symbiotic network can be reflected by the economic, environmental, material reduction cycle and the network structure association degree analysis. The overall level of ecological efficiency and the state of network stability further verify the feasibility and operability of the evaluation index system and evaluation model.