Abstract:One of the important measures to realize the high-quality development of urban economy is to optimize the industrial structure and enhance the green total factor productivity (GTFP). Taking 34 central cities in Northeast China as samples, this paper uses econometric model to analyze the relationship between the rationalization of industrial structure, the advanced industrial structure, the industrial specialized cluster and the agglomeration of industrial diversification and the GTFP . The results show that: The effect of rationalization of industrial structure on GTFP is realized by improving technological efficiency and investment biased technological progress. The upgrading of industrial structure has an impact on GTFP through the improvement of technological efficiency and output biased technological progress. The industrial specialized cluster has an impact on GTFP by improving technological efficiency and neutral technological progress. The impact of agglomeration of industrial diversification on GTFP is related to the mediating effect of technological efficiency, output biased technological and neutral technological progress.