Abstract:Innovation is an important means to achieve sustainable development in the heavily polluted industry. To maintain the sustainable resilience of innovation and incorporate ESG concepts into business operations, it is necessary to focus on the continuous generation mechanism of value-driven by innovation. Based on the data of listed companies in the heavily polluted industry from 2011 to 2020, the PVAR model was used to study the linkage effect of R D investment, ESG, and corporate value. The study found that: (1) R&D investment drives corporate value, and ESG has a unidirectional linkage with R D investment. The mutual causal effect between ESG and R D investment is mainly contributed by corporate governance, while the bidirectional interaction effect between ESG and corporate value is mainly contributed by social responsibility. (2) The value return of R D investment lags behind, and the lack of sustainable resilience coexists with the insufficiency of R D investment related to environmental responsibility. (3) Small and high-growth enterprises have inadequate conversion and interaction of ESG and R D investment towards corporate value.