Abstract:Under the background of developing new quality productivity, the behavior of enterprises, as an important carrier of independent innovation and promotion of green technological progress, plays a decisive role in ecological environment management, and it has become an important issue of concern for academics and the industry to explore the driving factors of enterprises' green technological innovation based on the external stakeholders and internal strategic decision-makers' qualities. From the perspective of informal environmental regulation, the article explores the impact of ESG ratings on firms' radical green technology innovation and the underlying mechanisms with the help of panel data of listed companies in the heavy pollution industry from 2011 to 2020. It is found that higher ESG ratings can effectively promote firms' radical green technology innovation. Mechanism identification reveals that ESG ratings can promote radical green technological innovation by increasing the level of corporate risk-taking, and that the environmental awareness of executives strengthens the promotional relationship between ESG ratings and corporate radical green technological innovation; furthermore, there is heterogeneity in the impact of ESG ratings on corporate radical green technological innovation in different contexts, and ESG ratings as an informal environmental regulation are different from those as a formal environmental regulation in the promotion of corporate radical green technological innovation. ESG ratings as informal environmental regulation and formal environmental regulation complement each other in promoting firms' radical green technological innovation.